Gamma-Heptalactone
Synthétique
Fruity > Lactonic > Coconut > Coumarinic > Tobacco
Crédits photo: ScenTree SAS
Other names :
Heptanolide-1,4 ; Heptan-4-olide ; Heptanolide-4,1 ; 4-Hydroxyheptanoic acid lactone ; heptano-1,4-lactone
Volatility :
Base
Uses in perfumery :
This lactone differs from the others by its very creamy side. It is recommended to use it to bring creamy facets to vanilla, coconut or gardenia reconstitutions.
Natural availability :
Gamma-Heptalactone can be found in trace amounts (< 0.5%) in Bergamot EO, in the fruit of the Jujube tree (Zizyphus jujuba), in peach, strawberry, papaya, beer or black tea. There are too few to make a natural extraction economically interesting. However, some companies are using natural qualities derived from biotechnology. The resulting price is particularly high.
Year of discovery :
Data not available.
Other comments :
Data not available.
Price Range :
€€€
Stability :
Lactones tend to polymerize through time, making them more viscous and leading to a phase shift in alcohol.
Crédits photo: ScenTree SAS
- Molecular formula :
- C7H12O2
- Molecular Weight :
- 128,17 g/mol
- Density :
- 1,000
- Flash Point :
- 105°C
- Fusion Point :
- Donnée indisponible.
- Appearance :
- Colorless liquid
- Log P :
- 1,09
- Boiling Point :
- 230 °C
- Detection Threshold :
- Donnée indisponible.
Synthesis route :
Gamma-Heptalactone is a cyclic lactone synthesized in the similar way as other lactones. The reaction between acrylic acid and butanol, in the presence of an alkaline sulphate or phosphate allows this molecule to be synthesized. Intramolecular esterification of 4-hydroxyheptanoic acid, catalyzed by a strong acid such as concentrated sulfuric acid, also makes it possible. Finally, biochemical synthesis routes are being studied by the producing companies.
Synthesis precursor :
Gamma-Heptalactone is not a precursor to the synthesis of another compound of olfactory interest.
Isomerism :
Gamma-Heptalactone has an asymetric carbon. The odor of the two enantiomers of this molecule is similar so, we always use its racemic mixture in perfumery. Cis-3-Hexenyl Formate is a constituent isomer of Heptalactone-gamma, but has a very different green odor.
- EINECS number :
- 203-279-9
- FEMA number :
- 2539
- JECFA number :
- 225
- FLAVIS number :
- 10.020
- Allergens :
- This ingredient does not contain any allergen.
- IFRA :
- This ingredient is not restricted
To learn more about IFRA's standards : https://ifrafragrance.org/safe-use/library
ScenTree is solely responsible for the information provided here.
