Photo credits: ScenTree SAS
| Company | Ingredient Name | ID | Comments | Naturality | Certifications | Purity | Latin name | Treated part | Geographical origin | MOQ |
|---|---|---|---|---|---|---|---|---|---|---|
|
Menthol - 30 Gr | - |
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- | - | - | - | - | - | |
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MENTHONE L-23 | M_0050650 |
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Naturel | - | - | - | - | - | |
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L-Menthol FCC | 30564715 |
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|
Molecule | - | - | - | - | - | |
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L-Menthol FCC BMBcert™ | 30775033 |
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|
Molecule | - | - | - | - | - | |
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L-Menthol Flakes FCC | 30564716 |
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|
Molecule | - | - | - | - | - | |
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L-Menthol Flakes FCC BMBcert™ | 30775034 |
Visit website
|
Molecule | - | - | - | - | - |
Menthol - 30 Gr
Certifications :
MENTHONE L-23
ID : M_0050650
Certifications :
L-Menthol FCC
ID : 30564715
Certifications :
L-Menthol FCC BMBcert™
ID : 30775033
Certifications :
L-Menthol Flakes FCC
ID : 30564716
Certifications :
L-Menthol Flakes FCC BMBcert™
ID : 30775034
Certifications :
General Presentation
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CAS N° : 2216-51-5
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EINECS number : 218-690-9
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FEMA number : 2665
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FLAVIS number : Donnée indisponible.
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JECFA number : Donnée indisponible.
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Appearance : White solid
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Density : 0,89
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Volatility : Head
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Price Range : €€
Physico-chemical properties
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Molecular formula : C10H20O
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Molecular Weight : 156,27 g/mol
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Log P : 3,15
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Fusion Point : 42°C
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Boiling Point : 219°C
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Detection Threshold : Donnée indisponible.
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Optical rotation : Donnée indisponible
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Vapor pressure : Donnée indisponible
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Refractive Index @20°C : Donnée indisponible
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Acid Value : Donnée indisponible.
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Flash Point : 94°C
Uses
Uses in perfumery :
L-Menthol is used in mint reconstitutions, in men perfumes, to boost top note.
Year of discovery :
1907
Natural availability :
L-Menthol is mostly produced naturally from Corn Mint EO at more than 15 000 tonnes per year. The essential oil contains up to 80% L-Menthol and can be glazed to crystallize L-Menthol, separated from the oil by centrifugation. A recrystallization is necessary to obtain a greater purity. Then, the essential oil contains 30 to 50% of Menthone® that can be mobilized again to produce hemi-synthetic L-Menthol. A catalytic hydrogenation of the oil forms L-Menthol and D-Neomenthol. The present menthyl esters are saponified and a new crystallization of L-Menthol takes place. Peppermint EO can also be used to extract natural L-Menthol.
Isomerism :
Menthol has four pairs of isomers (laevorotatory and dextrorotatory), derived from the presence of three asymmetric carbons in the molecule. Menthol, NeoMenthol, IsoMenthol and IsoneoMenthol are part of the isomers mixture. Only L-Menthol causes a sensation of cold during olfaction and is the most often used in perfumery. Citronellol, Dihydromyrcenol and Patchone® are among the L-Menthol isomers. These have very different smells from L-Menthol, as they are more floral or earthy and woody.
Synthesis precursor :
Like its isomers, L-Menthol is a precursor to the synthesis of several compounds of olfactory interest. A catalytic hydrogenation of the molecule leads to the formation of para-Menthan. An oxidation by chromic acid or dehydrogenation leads to the synthesis of Menthone®. A dehydrogenation without catalyst leads to the formation of 3-para-Menthene. Finally, in the presence of an acid catalyst, an esterification with carboxylic acids synthesizes menthyl esters. An esterification with benzoic acid is used on an industrial scale for the resolution of a racemic L-Menthol.
Synthesis route :
L-Menthol can be synthesized in several ways. The first one is the result of dextrorotatory Citronellal cyclization (obtained naturally or from Myrcene), by reaction with a Lewis acid such as zinc chloride. The product obtained is a mixture of Isopulegol isomers (the laevorotatory isomer being obtained in majority). Then, the isomers of Isopulegol can be separated to recover the laevorotatory component and synthesize L-Menthol by a catalytic hydrogenation. This hydrogenation can also take place before the separation of the L-Menthol (which then, would have to be esterified). A second route of synthesis starts from laevorotatory piperitone which is hydrogenated in the presence of a Raney nickel catalyst. A mixture of L-Menthol isomers is obtained. The isomers are separated by saponification and crystallization, through an esterification reaction of the L-Menthol. A third process starts from the dextrorotatory Delta-3-Carene, present in Turpentine EO. It is isomerized into dextrorotatory 2-Carene and pyrolyzed to trans-2,8-p-Menthadiene. Isomerizing the latter synthesizes dextrorotatory Isoterpinolene. A catalytic hydrogenation gives dextrorotatory 3-para-Menthene. A final step of epoxidation, followed by a rearrangement and a catalytic hydrogenation of the compound obtained forms a mixture of Menthol, separable by fractional distillation. There is a last rather complex process starting from Thymol. This process is not detailed here.
Regulations & IFRA
Allergens :
This ingredient does not contain any allergen.
IFRA 51th :
This ingredient is not restricted for the 51th amendment
